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Ultra-high vacuum scanning tunneling microscopy (UHV-STM) was used to investigate two related molecules pulse-deposited onto Au(111) surfaces: indoline-2-carboxylic acid and proline (pyrrolidine-2-carboxylic acid). 

Abstract Quasi-linear convective systems (QLCSs) are responsible for approximately a quarter of all tornado events in the U.S., but no field campaigns have focused specifically on collecting data to understand QLCS tornadogenesis. The Propagation, Evolution, and Rotation in Linear System (PERiLS) project was the first observational study of tornadoes associated with QLCSs ever undertaken. Participants were drawn from more than 10 universities, laboratories, and institutes, with over 100 students participating in field activities. The PERiLS field phases spanned two years, late winters and early springs of 2022 and 2023, to increase the probability of intercepting significant tornadic QLCS events in a range of large-scale and local environments. The field phases of PERiLS collected data in nine tornadic and nontornadic QLCSs with unprecedented detail and diversity of measurements. The design and execution of the PERiLS field phase and preliminary data and ongoing analyses are shown. 

Abstract The Local Volume Complete Cluster Survey is an ongoing program to observe nearly a hundred low-redshift X-ray-luminous galaxy clusters (redshifts 0.03 <z< 0.12 and X-ray luminosities in the 0.1–2.4 keV bandL_X500c> 10⁴⁴erg s⁻¹) with the Dark Energy Camera, capturing data in theu,g,r,i,zbands with a 5σpoint source depth of approximately 25th–26th AB magnitudes. Here, we map the aperture masses in 58 galaxy cluster fields using weak gravitational lensing. These clusters span a variety of dynamical states, from nearly relaxed to merging systems, and approximately half of them have not been subject to detailed weak lensing analysis before. In each cluster field, we analyze the alignment between the 2D mass distribution described by the aperture mass map, the 2D red-sequence (RS) galaxy distribution, and the brightest cluster galaxy (BCG). We find that the orientations of the BCG and the RS distribution are strongly aligned throughout the interiors of the clusters: the median misalignment angle is 19° within 2 Mpc. We also observe the alignment between the orientations of the RS distribution and the overall cluster mass distribution (by a median difference of 32° within 1 Mpc), although this is constrained by galaxy shape noise and the limitations of our cluster sample size. These types of alignment suggest long-term dynamical evolution within the clusters over cosmic timescales. 

Abstract. Accurate boundary layer temperature and humidity profiles are crucial for successful forecasting of fog, and accurate retrievals of liquid water path are important for understanding the climatological significance of fog. Passive ground-based remote sensing systems such as microwave radiometers (MWRs) and infrared spectrometers like the Atmospheric Emitted Radiance Interferometer (AERI), which measures spectrally resolved infrared radiation (3.3 to 19.2 µm), can retrieve both thermodynamic profiles and liquid water path. Both instruments are capable of long-term unattended operation and have the potential to support operational forecasting. Here we compare physical retrievals of boundary layer thermodynamic profiles and liquid water path during 12 cases of thin (LWP<40 g m−2) supercooled radiation fog from an MWR and an AERI collocated in central Greenland. We compare both sets of retrievals to in-situ measurements from radiosondes and surface-based temperature and humidity sensors. The retrievals based on AERI observations accurately capture shallow surface-based temperature inversions (0–10 m a.g.l.) with lapse rates of up to −1.2 ∘C m−1, whereas the strength of the surface-based temperature inversions retrieved from MWR observations alone are uncorrelated with in-situ measurements, highlighting the importance of constraining MWR thermodynamic profile retrievals with accurate surface meteorological data. The retrievals based on AERI observations detect fog onset (defined by a threshold in liquid water path) earlier than those based on MWR observations by 25 to 185 min. We propose that, due to the high sensitivity of the AERI instrument to near-surface temperature and small changes in liquid water path, the AERI (or an equivalent infrared spectrometer) could be a useful instrument for improving fog monitoring and nowcasting, particularly for cases of thin radiation fog under otherwise clear skies, which can have important radiative impacts at the surface. 

Abstract This paper describes the development of U-net++ models, a type of neural network that performs deep learning, to emulate the shortwave Rapid Radiative-transfer Model (RRTM). The goal is to emulate the RRTM accurately in a small fraction of the computing time, creating a U-net++ that could be used as a parameterization in numerical weather prediction (NWP). Target variables are surface downwelling flux, top-of-atmosphere upwelling flux ( ), net flux, and a profile of radiative-heating rates. We have devised several ways to make the U-net++ models knowledge-guided, recently identified as a key priority in machine learning (ML) applications to the geosciences. We conduct two experiments to find the best U-net++ configurations. In Experiment 1, we train on non-tropical sites and test on tropical sites, to assess extreme spatial generalization. In Experiment 2, we train on sites from all regions and test on different sites from all regions, with the goal of creating the best possible model for use in NWP. The selected model from Experiment 1 shows impressive skill on the tropical testing sites, except four notable deficiencies: large bias and error for heating rate in the upper stratosphere, unreliable for profiles with single-layer liquid cloud, large heating-rate bias in the mid-troposphere for profiles with multi-layer liquid cloud, and negative bias at lowzenith angles for all flux components and tropospheric heating rates. The selected model from Experiment 2 corrects all but the first deficiency, and both models run ~10 4 times faster than the RRTM. Our code is available publicly. 

Abstract Land-atmosphere feedbacks are a critical component of the hydrologic cycle. Vertical profiles of boundary layer temperature and moisture, together with information about the land surface, are used to compute land-atmosphere coupling metrics. Ground based remote sensing platforms, such as the Atmospheric Emitted Radiance Interferometer (AERI), can provide high temporal resolution vertical profiles of temperature and moisture. When co-located with soil moisture, surface flux, and surface meteorological observations, such as at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site, it is possible to observe both the terrestrial and atmospheric legs of land-atmosphere feedbacks. In this study, we compare a commonly used coupling metric computed from radiosonde-based data to that obtained from the AERI to characterize the accuracy and uncertainty in the metric derived from the two distinct platforms. This approach demonstrates the AERI’s utility where radiosonde observations are absent in time and/or space. Radiosonde and AERI based observations of the Convective Triggering Potential and Low-Level Humidity Index (CTP-HI low ) were computed during the 1200 UTC observation time and displayed good agreement during both 2017 and 2019 warm seasons. Radiosonde and AERI derived metrics diagnosed the same atmospheric preconditioning based upon the CTP-HI low framework a majority of the time. When retrieval uncertainty was considered, even greater agreement was found between radiosonde and AERI derived classification. The AERI’s ability to represent this coupling metric well enabled novel exploration of temporal variability within the overnight period in CTP and HI low . Observations of CTP-HI low computed within a few hours of 1200 UTC were essentially equivalent, however with greater differences in time arose greater differences in CTP and HI low .